JJAP Conf. Proc. 8, 011103 (2020) doi:10.7567/JJAPCP.8.011103
Synthesis of CaF2 Nanostructures from Calcium Silicide Powders in Diluted Aqueous HF Solution
- 1Graduate School of Integrated Science and Technology, Shizuoka University, Hamamatsu, Shizuoka 432-8561, Japan
- 2Faculty of Engineering, Shizuoka University, Hamamatsu, Shizuoka 432-8561, Japan
- 3Graduate School of Science and Technology, Shizuoka University, Hamamatsu, Shizuoka 432-8561, Japan
- 4Research Institute of Electronics, Shizuoka University, Hamamatsu, Shizuoka 432-8561, Japan
- 5Yamaha Advanced Material Research Group, Yamaha Motor Co., Ltd., Iwata, Shizuoka 438-8501, Japan
- Received December 05, 2019
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CaF2 nanostructures were synthesized from Ca-silicide powders by a diluted aqueous HF treatment. Commercially-available CaSi2 crystal powders and calcium silicide powders prepared by mechanical alloying were used as the source materials, and CaF2 nanosheet bundles and nanobunches of the CaF2 nanoparticles were obtained, respectively. The morphological property of the resulting CaF2 nanostructures was characterized by electron microscopy. It was found that the morphology of the resulting products depended on the starting materials. In addition, the growth mechanism of the CaF2 nanostructures was discussed from a topological synthesis point of view.
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